The two on the left are the brothers of James Peter Auriol (in green on the main picture from two days ago), the seated gent with the hookah in his hand is John Prinsep the husband of Sophia, one of the sisters. James Auriol was an administrator in the East India Company. I found the picture quite intriguing - it's a tea party outside, but the weather looks very threatening and I assume it would be quite hot and humid and yet here they are in tight trousers and waistcoats and jackets, shirts with high collars, looking all cool and collected.
Interestingly, the picture is on loan from the Dashwood family.
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